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Unicode wants to be able to preserve round-trip re-encoding from this other standard which has separate letter-K and degree-K characters. Making these small sacrifices for compatibility is how Unicode became the defacto world standard.

The "other standard" in this case being IBM-944. (At least looking at https://www.unicode.org/versions/Unicode1.0.0/ch06.pdf p. 574 (=110 in the PDF) I only see a mapping from U+212A to that one.)
The ICU mappings files have entries for U212A in the following files:

    gb18030.ucm
    ibm-1364_P110-2007.ucm
    ibm-1390_P110-2003.ucm
    ibm-1399_P110-2003.ucm
    ibm-16684_P110-2003.ucm
    ibm-933_P110-1995.ucm
    ibm-949_P110-1999.ucm
    ibm-949_P11A-1999.ucm

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